NILE
CHEMICALS
NILE
CHEMICALS
Synonyms: Nickel (II) chloride
CAS No.: 7718-54-9 Anhydrous; (7791-20-0 Hexahydrate)
Molecular Weight: 237.7
Chemical Formula: NiCl2 6H2O
Product Codes: 141133
Ingredient CAS No Percent Hazardous
Nickel Chloride 7718-54-9 90 - 100% Yes
Inhalation: Causes irritation to the respiratory tract. Symptoms may
include metallic taste in mouth, coughing, sore throat, and shortness of breath.
Lung damage may result from a single high exposure or lower repeated exposures.
Lung allergy occasionally occurs, with asthma type symptoms.
Ingestion: Toxic. Symptoms may include abdominal pain, diarrhea, nausea,
and vomiting. Absorption is poor, but should it occur, symptoms may include
giddiness, capillary damage, myocardial weakness, central nervous system
depression, and kidney and liver damage.
Skin Contact: Causes irritation. May cause skin allergy with itching,
redness or rash. Some individuals may become sensitized to the substance and
suffer "nickel itch", a form of dermatitis.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: Prolonged or repeated exposure to excessive
concentrations may affect lungs, liver and kidneys. Chronic exposure to nickel
and nickel compounds is associated with cancer.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin
disorders, impaired respiratory or pulmonary function, or with a history of
asthma, allergies, or sensitization to nickel compounds may be at an increased
risk upon exposure to this substance.
Inhalation: Remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion: Induce vomiting immediately as directed by medical personnel.
Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15
minutes. Remove contaminated clothing and shoes. Get medical attention. Wash
clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15
minutes, lifting lower and upper eyelids occasionally. Get medical attention
immediately.
Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing
surrounding fire.
Special Information: In the event of a fire, wear full protective
clothing and NIOSH-approved self-contained breathing apparatus with full
facepiece operated in the pressure demand or other positive pressure mode.
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Solutions are acidic. Areas in which exposure to nickel metal or soluble nickel compounds may occur should be identified by signs or appropriate means, and access to the area should be limited to authorized persons. Wear special protective equipment (Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits: -OSHA Permissible Exposure
Limit (PEL):soluble Nickel compounds as Ni: 1 mg/m3 (TWA)-ACGIH Threshold Limit
Value (TLV):soluble Nickel compounds as Ni: 0.1 mg/m3 (TWA), A4 - Not
classifiable as a human carcinogen
Ventilation System: A system of local and/or general exhaust is
recommended to keep employee exposures below the Airborne Exposure Limits. Local
exhaust ventilation is generally preferred because it can control the emissions
of the contaminant at its source, preventing dispersion of it into the general
work area. Please refer to the ACGIH document, Industrial Ventilation, A
Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded
and engineering controls are not feasible, a full facepiece particulate
respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure
limit or the maximum use concentration specified by the appropriate regulatory
agency or respirator supplier, whichever is lowest. If oil particles (e.g.
lubricants, cutting fluids. glycerine, etc.) are present, use a NIOSH type R or
P filter. For emergencies or instances where the exposure levels are not known,
use a full-facepiece positive-pressure, air-supplied respirator. WARNING:
Air-purifying respirators do not protect workers in oxygen-deficient
atmospheres.
Skin Protection: Wear impervious protective clothing, including boots,
gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where
dusting or splashing of solutions is possible. Maintain eye wash fountain and
quick-drench facilities in work area.
Other Control Measures: Eating, drinking, and smoking should not be
permitted in areas where solids or liquids containing soluble nickel compounds
are handled, processed, or stored. NIOSH recommends pre-placement and periodic
medical exams, with maintaining of records for all employees exposed to nickel
in the workplace.
Appearance: Yellow or light green deliquescent
crystals.
Odor: Odorless.
Solubility: 2.54 kg/L @ 20C
Specific Gravity: 3.55
pH: ca. 4 Aqueous solution
% Volatiles by volume @ 21C (70F): 0
Boiling Point: ca. 973C (ca. 1783F) Sublimes.
Melting Point: ca. 1001C (ca. 1834F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): 1 @ 671C (1240F)
Evaporation Rate (BuAc=1): No information found.
Stability: Stable under ordinary conditions of use
and storage. Substance will pick up moisture from the air and go into solution
if exposed in open containers.
Hazardous Decomposition Products: Oxides of the contained metal and
halogen, possibly also free, or ionic halogen.
Hazardous Polymerization: Will not occur.
Incompatibilities: Violent reaction with potassium.
Conditions to Avoid: Moisture and incompatibles
Nickel Chloride: Oral rat LD50: 105 mg/kg. Investigated as a tumorigen, mutagen, reproductive effector.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Nickel Chloride (7718-54-9) Yes No 1
Environmental Fate: No information found.
Environmental Toxicity: This material is expected to be toxic to aquatic
life. The LC50/96-hour values for fish are between 10 and 100 mg/l.
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: RQ, TOXIC SOLID, INORGANIC, N.O.S. (NICKELOUS
CHLORIDE, 6-HYDRATE)
Hazard Class: 6.1
UN/NA: UN3288
Packing Group: III
Information reported for product/size: 100LB
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (NICKELOUS CHLORIDE,
6-HYDRATE)
Hazard Class: 6.1
UN/NA: UN3288
Packing Group: III
Information reported for product/size: 100LB
International (Air, I.C.A.O.)
-----------------------------
Proper Shipping Name: TOXIC SOLID, INORGANIC, N.O.S. (NICKELOUS CHLORIDE,
6-HYDRATE)
Hazard Class: 6.1
UN/NA: UN3288
Packing Group: II
Information reported for product/size: 100LB
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Nickel Chloride (7718-54-9) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Nickel Chloride (7718-54-9) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Nickel Chloride (7718-54-9) No No No Nickel compo
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Nickel Chloride (7718-54-9) 100 No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Pure / Solid)
WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS: This MSDS has been prepared according to the hazard criteria of
the Controlled Products Regulations (CPR) and the MSDS contains all of the
information required by the CPR.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICLAS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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