NILE
CHEMICALS
NILE
CHEMICALS
Synonyms: Nickel (II) nitrate, CAS No.: 13138-45-9 Anhydrous; (13478-00-7 Hexahydrate)
Molecular Weight: 290.83
Chemical Formula: Ni(NO3)2 6H2O
Product Codes: 141134
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------ ---------
Nickel Nitrate 13138-45-9 90 - 100% Yes
Potential Health Effects
----------------------------------
Inhalation: Causes irritation to the respiratory tract. Symptoms may
include coughing, sore throat, and shortness of breath. Lung damage may result
from a single high exposure or lower repeated exposures. Lung allergy
occasionally occurs, with asthma type symptoms.
Ingestion: Toxic. Symptoms may include abdominal pain, diarrhea, nausea,
and vomiting. Absorption is poor, but should it occur, symptoms may include
giddiness, capillary damage, myocardial weakness, central nervous system
depression, and kidney and liver damage.
Skin Contact: Causes irritation. May cause skin allergy with itching,
redness or rash. Some individuals may become sensitized to the substance and
suffer "nickel itch", a form of dermatitis.
Eye Contact: Causes irritation, redness, and pain.
Chronic Exposure: Prolonged or repeated exposure to excessive
concentrations may affect lungs, liver and kidneys. Chronic exposure to nickel
and nickel compounds is associated with cancer.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin
disorders, impaired respiratory or pulmonary function, or with a history of
asthma, allergies, or sensitization to nickel compounds may be at an increased
risk upon exposure to this substance.
Inhalation: Remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Ingestion: Induce vomiting immediately as directed by medical personnel.
Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush
skin with plenty of water for at least 15 minutes. Remove contaminated clothing
and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean
shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15
minutes, lifting lower and upper eyelids occasionally. Get medical attention
immediately.
Fire: Not combustible, but substance is a strong
oxidizer and its heat of reaction with reducing agents or combustibles may cause
ignition. Increases the flammability of any combustible material.
Explosion: Contact with oxidizable substances may cause extremely violent
combustion. Strong oxidants may explode when shocked, or if exposed to heat,
flame, or friction. Also may act as initiation source for dust or vapor
explosions.
Fire Extinguishing Media: Water or water spray in early stages of fire.
Foam or dry chemical may also be used.
Special Information: Wear full protective clothing and breathing
equipment for high-intensity fire or potential explosion conditions.
Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Areas in which exposure to nickel metal or soluble nickel compounds may occur should be identified by signs or appropriate means, and access to the area should be limited to authorized persons. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits: -OSHA Permissible Exposure
Limit (PEL):
soluble Nickel compounds as Ni: 1 mg/m3 (TWA)-ACGIH Threshold Limit Value (TLV):soluble
Nickel compounds as Ni: 0.1 mg/m3 (TWA), A4 - Not classifiable as a human
carcinogen
Ventilation System: A system of local and/or general exhaust is
recommended to keep employee exposures below the Airborne Exposure Limits. Local
exhaust ventilation is generally preferred because it can control the emissions
of the contaminant at its source, preventing dispersion of it into the general
work area. Please refer to the ACGIH document, Industrial Ventilation, A
Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded
and engineering controls are not feasible, a full facepiece particulate
respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure
limit or the maximum use concentration specified by the appropriate regulatory
agency or respirator supplier, whichever is lowest. If oil particles (e.g.
lubricants, cutting fluids. glycerine, etc.) are present, use a NIOSH type R or
P filter. For emergencies or instances where the exposure levels are not known,
use a full-facepiece positive-pressure, air-supplied respirator. WARNING:
Air-purifying respirators do not protect workers in oxygen-deficient
atmospheres.
Skin Protection: Rubber or neoprene gloves and additional protection
including impervious boots, apron, or coveralls, as needed in areas of unusual
exposure.
Eye Protection: Use chemical safety goggles and/or full face shield where
dusting or splashing of solutions is possible. Maintain eye wash fountain and
quick-drench facilities in work area.
Other Control Measures: Eating, drinking, and smoking should not be
permitted in areas where solids or liquids containing soluble nickel compounds
are handled, processed, or stored. NIOSH recommends pre-placement and periodic
medical exams, with maintaining of records for all employees exposed to nickel
in the workplace.
Appearance: Green, transparent crystals.
Odor: Odorless.
Solubility: 238.5g/100cc water @ 0C
Specific Gravity: 2.05
pH: 3.5 - 5.5 (5% solution @ 25C (77F).
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 137C (279F)
Melting Point: 56.7C (135F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): 0 @ 20C (68F)
Evaporation Rate (BuAc=1): No information found.
Stability: Stable under ordinary conditions of use
and storage. Substance has both oxidant and reducing characteristics, and is
unstable when heated or shocked.
Hazardous Decomposition Products: Emits toxic fumes of nickel and
nitrogen oxides when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Aluminum, boron phosphide, cyanides, esters,
combustible material, phospham, phosphorus, sodium hypophosphite, stannous
chloride, thiocyanates, strong reducing agents, and organic materials.
Conditions to Avoid: Heat, shock, friction, incompatibles.
Nickelous Nitrate Hexahydrate; Oral rat LD50: 1620 mg/kg. Investigated as a tumorigen.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Nickel Nitrate (13138-45-9) Yes No 1
Environmental Fate: When released into water, this
material is not expected to evaporate significantly. This material is not
expected to significantly bioaccumulate.
Environmental Toxicity: Dangerous to the environment. Very toxic to
aquatic organisms; may cause long term adverse effects in the aquatic
environment.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: NICKEL NITRATE
Hazard Class: 5.1
UN/NA: UN2725
Packing Group: III
Information reported for product/size: 4X25LB
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: NICKEL NITRATE
Hazard Class: 5.1
UN/NA: UN2725
Packing Group: III
Information reported for product/size: 4X25LB
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Nickel Nitrate (13138-45-9) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Nickel Nitrate (13138-45-9) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Nickel Nitrate (13138-45-9) No No No Nickel cmpd/
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Nickel Nitrate (13138-45-9) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: Yes (Pure / Solid)
WARNING: THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN
TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
Australian Hazchem Code: 1Y
Poison Schedule: None allocated.
WHMIS: This MSDS has been prepared according to the hazard criteria of
the Controlled Products Regulations (CPR) and the MSDS contains all of the
information required by the CPR.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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