NILE
CHEMICALS
SODIUM BISELENITE MSDS
  Product Number 191148
  Company Nile Chemicals
  Mumbai
  INDIA
  Technical Phone # 91-22-6631 3162
  Fax 91-22-2345 4828
  ________________________________________________________________________
  2 - Hazards Identification
  ________________________________________________________________________
  SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE
  ENVIRONMENT
  Toxic by inhalation and if swallowed. Danger of
  cumulative
  effects. Very toxic to aquatic organisms, may
  cause long-term
  adverse effects in the aquatic environment.
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  3 - Composition/Information on Ingredients
  ________________________________________________________________________
  Product Name CAS # EC no Annex I
  Index Number
  SODIUM HYDROGEN SELENITE 7782-82-3 231-966-3
  034-002-00-8
  Formula NaHSeO3
  Molecular Weight 150,9600 AMU
  Synonyms Hydrogen sodium selenite * Hydrogen
  sodium
  selenium oxide * Sodium hydrogen trioxoselenite
  * Sodium hydroselenite * Sodium selenite (7CI)
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  4 - First Aid Measures
  ________________________________________________________________________
  AFTER INHALATION
  If inhaled, remove to fresh air. If not
  breathing give
  artificial respiration. If breathing is
  difficult, give oxygen.
  AFTER INGESTION
  If swallowed, wash out mouth with water
  provided person is
  conscious. Call a physician immediately.
  ________________________________________________________________________
  5 - Fire Fighting Measures
  ________________________________________________________________________
  EXTINGUISHING MEDIA
  Suitable: Noncombustible. Use extinguishing
  media appropriate to
  surrounding fire conditions.
  SPECIAL RISKS
  Material Safety Data Sheet
  1 - Product and Company Information
  Specific Hazard(s): Emits toxic fumes under
  fire conditions.
  SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
  Wear self-contained breathing apparatus and
  protective clothing
  to prevent contact with skin and eyes.
  ________________________________________________________________________
  6 - Accidental Release Measures
  ________________________________________________________________________
  PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED
  IN CASE OF LEAK OR SPILL
  Evacuate area.
  PROCEDURE(S) OF PERSONAL PRECAUTION(S)
  Wear self-contained breathing apparatus, rubber
  boots, and heavy
  rubber gloves. Wear disposable coveralls and
  discard them after
  use.
  METHODS FOR CLEANING UP
  Sweep up, place in a bag and hold for waste
  disposal. Avoid
  raising dust. Ventilate area and wash spill
  site after material
  pickup is complete.
  ________________________________________________________________________
  7 - Handling and Storage
  ________________________________________________________________________
  HANDLING
  Directions for Safe Handling: Do not breathe
  dust. Do not get in
  eyes, on skin, on clothing. Avoid all contact.
  STORAGE
  Conditions of Storage: Keep tightly closed.
  Store in a cool dry
  place.
  ________________________________________________________________________
  8 - Exposure Controls / Personal Protection
  ________________________________________________________________________
  ENGINEERING CONTROLS
  Safety shower and eye bath. Use only in a
  chemical fume hood.
  GENERAL HYGIENE MEASURES
  Wash contaminated clothing before reuse.
  PERSONAL PROTECTIVE EQUIPMENT
  Special Protective Measures: Wear appropriate
  government approved
  respirator, chemical-resistant gloves, safety
  goggles, other
  protective clothing.
  ________________________________________________________________________
  9 - Physical and Chemical Properties
  ________________________________________________________________________
  Appearance Color: Almost white
  Form: Powder
  Property Value At Temperature or Pressure
  pH 6,0. - 7,0.
  BP/BP Range N/A
  MP/MP Range N/A
  Flash Point N/A
  Flammability N/A
  Autoignition Temp N/A
  Oxidizing Properties N/A
  Explosive Properties N/A
  Explosion Limits N/A
  Vapor Pressure N/A
  Partition Coefficient N/A
  Viscosity N/A
  Vapor Density N/A
  Saturated Vapor Conc. N/A
  Evaporation Rate N/A
  Bulk Density N/A
  Decomposition Temp. N/A
  Solvent Content N/A
  Water Content N/A
  Surface Tension N/A
  Conductivity N/A
  Miscellaneous Data N/A
  Solubility N/A
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  10 - Stability and Reactivity
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  STABILITY
  Stable: Stable.
  Materials to Avoid: Strong oxidizing agents,
  Strong acids.
  HAZARDOUS DECOMPOSITION PRODUCTS
  Hazardous Decomposition Products:
  Selenium/selenium oxides.
  HAZARDOUS POLYMERIZATION
  Hazardous Polymerization: Will not occur
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  11 - Toxicological Information
  ________________________________________________________________________
  RTECS NUMBER: VS7500000
  ACUTE TOXICITY
  LD50
  Oral
  < 50,000000 mg/kg
  SIGNS AND SYMPTOMS OF EXPOSURE
  To the best of our knowledge, the chemical,
  physical, and
  toxicological properties have not been
  thoroughly investigated.
  ROUTE OF EXPOSURE
  Multiple Routes: May cause irritation. May be
  fatal if inhaled,
  swallowed, or absorbed through skin.
  CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
  Species: Rat
  Dose: 15120 UG/KG
  Route of Application: Oral
  Exposure Time: (6W MALE)
  Result: Paternal Effects: Testes, epididymis,
  sperm duct.
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  12 - Ecological Information
  ________________________________________________________________________
  No data available.
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  13 - Disposal Considerations
  ________________________________________________________________________
  SUBSTANCE DISPOSAL
  Bury in a landfill site approved for the
  disposal of chemical and
  hazardous wastes. Observe all federal, state,
  and local
  environmental regulations.
  ________________________________________________________________________
  14 - Transport Information
  ________________________________________________________________________
  RID/ADR
  UN#: 2630
  Class: 6.1
  PG: I
  Proper Shipping Name: Selenites
  IMDG
  UN#: 2630
  Class: 6.1
  PG: I
  Proper Shipping Name: Selenites
  Marine Pollutant: No
  Severe Marine Pollutant: No
  IATA
  UN#: 2630
  Class: 6.1
  PG: I
  Proper Shipping Name: Selenites
  Inhalation Packing Group I: No
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  15 - Regulatory Information
  ________________________________________________________________________
  CLASSIFICATION AND LABELING ACCORDING TO EU
  DIRECTIVES
  ANNEX I INDEX NUMBER: 034-002-00-8
  NOTA: A
  INDICATION OF DANGER: T-N
  Toxic. Dangerous for the environment.
  R-PHRASES: 23/25-33-50/53
  Toxic by inhalation and if swallowed. Danger of
  cumulative
  effects. Very toxic to aquatic organisms, may
  cause long-term
  adverse effects in the aquatic environment.
  S-PHRASES: 20/21-28-45-60-61
  When using do not eat, drink, or smoke. After
  contact with
  skin, wash immediately with plenty of
  soap-suds. In case of
  accident or if you feel unwell, seek medical
  advice immediately
  (show the label where possible). This material
  and its
  container must be disposed of as hazardous
  waste. Avoid release
  to the environment. Refer to special
  instructions/safety data
  sheets.
  COUNTRY SPECIFIC INFORMATION
  Germany
  WGK: 3
  Self-Classification
  ________________________________________________________________________
  16 - Other Information
  ________________________________________________________________________
  WARRANTY
  The above information is believed to be correct
  but does not
  purport to be all inclusive and shall be used
  only as a guide. The
  information in this document is based on the
  present state of our
  knowledge and is applicable to the product with
  regard to
  appropriate safety precautions. It does not
  represent any
  guarantee of the properties of the product.
  Nile Chemicals,
  shall not be held liable for any damage
  resulting from handling or
  from contact with the above product.
  DISCLAIMER
  For R&D use only. Not for drug,
  household or other uses. 
 
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